The s32sysf.dll file is a part of the Symantec SysFiles API Library from Symantec, Inc. This is a piece of the Symantec Core Technology that is used as a base by various Symantec programs. Symantec builds a number of popular programs, including some security software that is commonly used. Errors with this file may indicate a problem in any Symantec software running on your computer, and could possibly mean your security system is not working correctly. You should clean your registry to solve the issue.
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